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<br>地址：江蘇省通州灣江海聯動開發示范區東海大道88號</span><br></span></div> </div> </div> </div></div></div><style class="column_class qfy_style_class">@media only screen and (min-width: 992px){.qfy-column-1-5e1f0a004a990350895 > .column_inner {padding-left:0;padding-right:0;padding-top:11px;padding-bottom:0;}.qfe_row .vc_span_class.qfy-column-1-5e1f0a004a990350895 {};}@media only screen and (max-width: 992px){.qfy-column-1-5e1f0a004a990350895 > .column_inner{margin:0 auto 0 !important;min-height:0 !important;padding-left:0;padding-right:0;padding-top:0;padding-bottom:0;}.display_entire .qfe_row .vc_span_class.qfy-column-1-5e1f0a004a990350895 {}.qfy-column-1-5e1f0a004a990350895 > .column_inner> .background-overlay,.qfy-column-1-5e1f0a004a990350895 > .column_inner> .background-media{width:100% !important;left:0 !important;right:auto !important;}}</style><div data-animaleinbegin="bottom-in-view" data-animalename="qfyfadeInUp" data-duration="" data-delay="" class=" qfy-column-2-5e1f0a008a75c697103 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{#vc_header_5e1f0a008ae83926 .header_subtitle{font-size:20px !important;}}</style> <div class="qfe_wrapper"> <h1 class="qfy_title left mobileleft"> <div class="qfy_title_inner" style="display:inline-block;position:relative;max-width:100%;"> <div class="header_title" style="font-family:微軟雅黑;font-size:26px;font-weight:normal;font-style:normal;color:#191919;"> 全網最全的總磷（TP）處理攻略，你了解嗎？ </div> </div> </h1> </div> </div> <div m-padding="0px 0px 0px 0px" p-padding="0 0 0 0" css_animation_delay="0" qfyuuid="qfy_column_text_mtoeb-c-9c" data-anitime="0.7" class="qfy-element qfy-text qfy-text-68107 qfe_text_column qfe_content_element newsdate " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:0;margin-bottom:20px;padding-top:0;padding-bottom:0;padding-right:0;padding-left:0;border-radius:0px;"> <div class="qfe_wrapper"> <div><span style="" class="qfy_no_editor pdate">2021/8/29</span></div> </div> </div> <div m-padding="0px 0px 70px 0px" p-padding="0 0 70px 0" css_animation_delay="0" qfyuuid="qfy_column_text_re2wu-c-9c" data-anitime="0.7" data-ani_iteration_count="1" class="qfy-element qfy-text qfy-text-85363 qfe_text_column qfe_content_element " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:10px;margin-bottom:0;padding-top:0;padding-bottom:70px;padding-right:0;padding-left:0;border-radius:0px;"> <div class="qfe_wrapper"> <section><section><section><section><p style="text-align:center"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(64, 118, 0); letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 255, 255);"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><img src="/admin888/ueditor/asp/upload/image/20210829/16302427271528547.png" title="image.png" alt="image.png" width="572" height="157" style="width: 572px; height: 157px;"/></span></strong></span></p></section><section><section><span style="background-color: rgb(255, 255, 0);"><strong>一、磷在廢水中存在的形式是什么？</strong></span></section></section></section></section></section><p><br/></p><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">磷是一種活潑元素，在自然界中不以游離狀態存在，而是以含磷有機物、無機磷化合物及還原態PH</span><sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;">3</sub><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">這三種狀態存在。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">污水中含磷化合物可分為有機磷與無機磷兩類。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">無機磷幾乎都以各種磷酸鹽形式存在，包括正磷酸鹽、偏磷酸鹽、磷酸氫鹽、磷酸二氫鹽，以及聚合磷酸鹽如焦磷酸鹽、三磷酸鹽等。有機磷大多是有機磷農藥，如樂果、甲基對硫磷、乙基對硫磷、馬拉硫磷等構成，他們大多呈膠體和顆粒狀，不溶于水，易溶于有機溶劑?？扇苄杂袡C磷只占30%左右，多以葡萄糖-6-磷酸、2-磷酸-甘油酸及磷肌酸等形式存在。溶解磷占總磷的1/3 左右，PO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">4</sub><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">ˉ</sup>-P磷中大分子磷占40%。</span></section><section><br/></section><section><section><section><section><p><span style="background-color: rgb(255, 255, 0);"><strong>二、磷是怎樣轉化的？影響因素有哪些？</strong></span></p><p><br/></p></section></section></section></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">水體中的可溶性磷很容易與Ca</span><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;">2+</sup><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">、Fe</span><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;">3+</sup><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">、Al</span><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;">3+</sup><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">等離子生成難溶性沉淀物，例如AIPO</span><sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;">4</sub><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">、FePO</span><sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;">4</sub><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">等，沉積于水體底部成為底泥。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">聚積于底泥中的磷的存在形式和數量，一方面決定于污染物輸入和通過地表與地下徑流的排出情況;另一方面決定于水中的磷與底泥中的磷之間的交換情況。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">沉積物中的磷通過顆粒態磷的懸浮和水流的湍流擴散再度被稀釋到上層水體中，或者當沉積物中的可溶性磷大大超過水體中磷的濃度時，則可能重新釋放到水體中。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">在水中，磷離子以HPO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">4</sub><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">2</sup><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">ˉ</sup>還是以H<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">2</sub>PO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">4</sub><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">ˉ</sup>形式存在取決于pH值，當pH值在2～7時，水中磷酸鹽離子多數以H<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">2</sub>PO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">4</sub><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">ˉ</sup>形式存在，而pH值在7～12時，則水中的磷酸鹽離子多數以HPO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">4</sub><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">2</sup><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">ˉ</sup>形式存在。所有含磷化合物都是首先轉化為正磷酸鹽(PO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">4</sub><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">3</sup><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">ˉ</sup>) 后，再轉化為其他形式。此時測定PO的含量，測定結果即是總磷的含量。</span></section><p><br/></p><p><span style="background-color: rgb(255, 255, 0);"><strong>三、磷的來源是什么？</strong></span></p><section><section><section><section><section><br/></section></section></section></section></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">污水中的磷部分來源于化肥和農業廢棄物。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">同時，生活中含磷洗滌劑的大量使用也使生活污水中磷的含量顯著增加。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">此外，化工、造紙、橡膠、染料和紡織印染、農藥、焦化、石油化工、發酵、醫藥與醫療及食品等行業排放的廢水常含有有機磷化合物。</span></section><p><br/></p><p><span style="background-color: rgb(255, 255, 0);"><strong>四、磷的危害是什么？</strong></span></p><section><section><section><section><section><br/></section></section></section></section></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0); letter-spacing: 0.5px; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">1、磷對人體的危害</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">高磷洗衣粉對皮膚有直接刺激作用，嚴重的會導致接觸性皮膚炎、嬰兒尿布疹等疾病。同時磷會對神經中樞造成危害，特別是一部分有機磷農藥的生物降解性差，易在環境中殘留，對人、畜等脊椎動物具有相當高的毒性，會抑制膽堿酯酶的作用，影響神經系統功能，引起中毒甚至死亡。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0); letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">2、磷對海洋生物的危害</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">目前國內外廣泛使用的有機磷農藥對海洋生物危害巨大，有機磷能夠激活對蝦體內的潛伏病原體。魚、蝦等死亡事件層出不窮，已經對海水養殖業形成威脅。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0); letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">3、磷對土壤的污染</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">磷對土壤的污染主要來源于過量使用農藥、化肥及污水灌溉。過量的磷會超過土壤的自凈能力，使土壤發生不良變化，導致土壤自然正常功能失調。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">更嚴重的會導致毒化空氣和水質，通過植物吸收，降低農副產品生物學質量，造成殘毒通過植物鏈傳遞最終危害人類生命和健康。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0); letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">4、過量的磷對水體有較大危害，造成水體富營養化</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">對于引發水體富營養化而言，磷的作用遠大于氮的作用，水體中磷的濃度不是很高時就可以引起水體富營養化。</span><br/></section><section><br/></section><section><section><section><section><section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(64, 118, 0); letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 255, 255);"></strong></section></section><section><p><span style="background-color: rgb(255, 255, 0);"><strong>五、化學除磷的概念和工藝是什么？</strong></span></p><p><br/></p></section></section></section></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">化學除磷是通過化學沉淀過程完成的，化學沉淀是指通過向污水中投加藥劑，其與</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">污水中溶解性的鹽類，如磷酸鹽混合后，形成顆粒狀、非溶解性的物質，污水中進行的不僅僅是沉淀反應，同時還進行著化學絮凝反應。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">采用的藥劑一般有鋁鹽、鐵鹽(亞鐵鹽)、石灰、鐵鋁聚合物。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">化學沉淀工藝是按沉淀藥劑的投加位置來區分的，實際中常采用的有:前沉淀、同步沉淀和后沉淀。</span></section><section><p style="text-align:center"></p></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0); letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">1、前沉淀</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">在沉淀池前投加金屬沉淀劑到原水中。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">其一般需要設置產生渦流的裝置或者供給能量以滿足混合的需要。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">相應產生的沉淀產物(大塊狀的絮凝體)則在一次沉淀池中通過沉淀而被分離。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">如果生物段采用的是生物濾池，則不允許使用Fe</span><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;">2+</sup><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">藥劑，以防止對填料產生危害(產生黃銹)。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">前沉淀工藝特別適合于現有污水處理廠的改建(增加化學除磷措施)，因為通過這一工藝步驟不僅可以去除磷，而且可以減少生物處理設施的負荷。常用的沉淀藥劑主要是生灰和金屬鹽藥劑。經前沉淀后剩余磷酸鹽的含量為1.5～2.5mg/L,完全能滿足后續生物處理對磷的需要。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0); letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">2、同步沉淀</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">在生物處理過程中投加金屬沉淀劑。同步沉淀是使用最廣泛的化學除磷工藝，其工藝是將沉淀藥劑投加在曝氣池出水或二次沉淀池進水中，個別情況也有將藥劑投加在曝氣池進水或回流污泥渠(管)中。目前很多污水廠都采用同步沉淀，加藥對活性污泥的影響比較小。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">3、后沉淀</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">將沉淀、絮凝以及被絮凝物質的分離在一個與生物設施相分離的設施中進行，向出水中投加金屬沉淀劑，一般將沉淀藥劑投加到二次沉淀池后的一個混合池中，之后混合沉淀。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">并在其后設置絮凝池和沉淀池(或氣浮池)。</span></section><p><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">對于要求不嚴的受納水體，在后沉淀工藝中可采用石灰乳液藥劑，但必須對出水pH值加以控制，比如采用沼氣中的CO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">2</sub>進行中和。采用氣浮池可以比沉淀池更好地去除懸浮物和總磷，但因為需恒定供應空氣而運轉費用較高。</span></p><p><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><br/></span></p><section><span style="background-color: rgb(255, 255, 0);"><strong>六、生物除磷的原理及影響因素</strong></span></section><section><section><section><section><section><br/></section></section></section></section></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">廢水中磷的存在形態取決于廢水的類型，最常見的是磷酸鹽、聚磷酸鹽和有機磷。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">生活廢水的含磷量一般在10～15mg/L左右，其中70%是可溶性的。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">常規二級生物處理的出水中90%左右的磷以磷酸鹽的形式存在。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">在傳統的活性污泥法中，磷作為微生物正常生長所必需的元素用于微生物菌體的合成，并以生物污泥的形式排出，從而引起磷的去除，能夠獲得10%～30%的除磷效果。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">在某些情況下，微生物吸收的磷量超過了微生物正常生長所需要的磷量，這就是活性污泥的生物超量除磷現象，廢水生物除磷技術正是利用生物超量除磷的原理而發展起來的。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">1、生物除磷的原理：</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">根據霍爾米(Holmers) 提出的化學式，活性污泥的組成是C<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">118</sub>H<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">170</sub>O<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">51</sub>N<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">17</sub>P，由此可知，C: N: P=46 : 8: 1。如果廢水中N、P的含量低于此值，則需另行從外部投加;如等于此值，則在理論上應當是能夠全部攝取而加以去除的。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">生物除磷的基本原理是利用一種被稱為聚磷菌(也稱為除磷菌、磷細菌等)的細菌在厭氧條件下能充分釋放其細胞體內的聚合磷酸鹽(該過程稱為厭氧釋磷);而在好氧條件下又能超過其生理需要從水中吸收磷 (該過程稱為好氧吸磷)，并將其轉化為細胞體內的聚合磷酸鹽，從而形成富含磷的生物污泥，通過沉淀從系統中排出這種富磷污泥，達到從廢水中除磷的效果。聚磷菌的作用機理如圖所示。</span></section><section><p style="text-align:center"></p></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">①在厭氧區內的釋磷過程，在沒有溶解氧和硝態氮存在的厭氧條件下，兼性細菌通過發酵作用將溶解性BOD轉化為揮發性有機酸 (VFA)，聚磷菌吸收VFA并進入細胞內，同化合成為胞內碳源的儲存物——聚-β-羥基丁酸鹽(PHB)，所需的能量來源于聚磷菌將其細胞內的有機態磷轉化為無機態磷的反應，并導致磷酸鹽的釋放。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">②在好氧區內的吸磷過程，聚磷菌的活力得到恢復并以聚磷的形態儲存超出生長需要的磷量，通過對PHB的氧化代謝產生能量用于磷的吸收和聚磷的合成，能量以聚磷酸高能鍵的形式儲存起來，磷酸鹽從液相去除。產生的高磷污泥通過剩余污泥的形式得到排放，從而將磷從系統中去除。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">由上可知，聚磷菌在厭氧狀態下釋放磷獲取能量以吸收廢水中溶解性有機物，在好氧狀態下降解吸收的溶解性有機物獲取能量以吸收磷，在整個生物除磷過程中表現為PHB的合成與分解。三磷酸腺苷(ATP)則作為能量的傳遞者。PHB的合成與分解作為一種能量的儲存和釋放過程，在聚磷菌的攝磷和放磷過程中起著十分重要的作用，即聚磷菌對PHB合成能力的大小將直接影響其攝磷能力的高低。正是因為聚磷菌在厭氧好氧交替運行的系統中有釋磷和攝磷的作用，才使得它在與其他微生物的競爭中取得優勢，從而使除磷作用向正反應的方向進行。聚磷菌在厭氧條件下能夠將其體內儲存的聚磷酸鹽分解，以提供能量攝取廢水中的溶解性有機基質，合成并儲存PHB，這樣使得其在與其他微生物的競爭中，其他微生物可利用的基質減少，從而不能很好地生長。在好氧階段，由于聚磷菌的過量攝磷作用，使得活性污泥中的其他微生物得不到足夠的有機基質及磷酸鹽，也使聚磷菌在與其他微生物的競爭中獲得優勢。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0); overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; font-size: 15px; overflow-wrap: break-word !important;">2、生物除磷的影響因素：</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（1）溶解氧</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">溶解氧的影響包括兩個方面。首先必須在厭氧區中控制嚴格的厭氧條件，這直接關系到聚磷菌的生長狀況、釋磷能力及利用有機基質合成PHB的能力。由于DO的存在，一方面DO將作為最終電子受體而抑制厭氧菌的發酵產酸作用，妨礙磷的釋放;另一方面會耗盡能快速降解的有機基質，從而減少聚磷菌所需的脂肪酸產生量，造成生物除磷效果差。其次是在好氧區中要供給足夠的溶解氧，以滿足聚磷菌對其儲存的PHB進行降解，釋放足夠的能量供其過量攝磷之需，有效地吸收廢水中的磷。一般厭氧段的DO應嚴格控制在0.2mg/L以下，而好氧段的溶解氧控制在2.0mg/L左右。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（2）厭氧區硝態氮</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">硝態氮包括硝酸鹽氮和亞硝酸鹽氮，其存在同樣也會消耗有機基質而抑制聚磷菌對磷的釋放，從而影響在好氧條件下聚磷菌對磷的吸收。另一方面，硝態氮的存在會被部分生物聚磷菌(氣單胞菌)利用作為電子受體進行反硝化，從而影響其以發酵中間產物作為電子受體進行發酵產酸，從而抑制了聚磷菌的釋磷和攝磷能力及PHB的合成能力。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（3）溫度</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">溫度對除磷效果的影響不如對生物脫氮過程的影響那么明顯，因為在高溫、中溫、低溫條件下，不同的菌群都具有生物脫磷的能力，但低溫運行時厭氧區的停留時間要更長一些，以保證發酵作用的完成及基質的吸收。在5~30°C的范圍內，都可以得到很好的除磷效果。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（4） pH值</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">pH值在6～8的范圍內時，磷的厭氧釋放過程比較穩定。pH值低于6.5時生物除磷的效果會大大降低。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（5）BOD負荷和有機物性質</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">廢水生物除磷工藝中，厭氧段有機基質的種類、含量及其與微生物營養物質的比值(<span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important; background-image: initial; background-attachment: initial; background-size: initial; background-origin: initial; background-clip: initial; background-position: initial; background-repeat: initial;">BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">5</sub></span>/TP)是影響除磷效果的重要因素。不同的有機物為基質時，磷的厭氧釋放和好氧攝取是不同的。根據生物除磷原理，相對分子質量較小的易降解的有機物(如低級脂肪酸類物質)易于被聚磷菌利用，將其體內儲存的多聚磷酸鹽分解釋放出磷，誘導磷釋放的能力較強，而高分子難降解的有機物誘導釋磷的能力較弱。厭氧階段磷的釋放越充分，好氧階段磷的攝取量就越大。另一方面，聚磷菌在厭氧段釋放磷所產生的能量，主要用于其吸收進水中低分子有機基質合成PHB儲存在體內，以作為其在厭氧條件壓抑環境下生存的基礎。因此，進水中是否含有足夠的有機基質提供給聚磷菌合成PHB，是關系到聚磷菌在厭氧條件下能否順利生存的重要因素。一般認為，進水中BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">5</sub>/TP要大于15才能保證聚磷菌有足夠的基質需求而獲得良好的除磷效果。為此，有時可以采用部分進水和省去初次沉淀池的方法來獲得除磷所需的BOD負荷。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.544px; overflow-wrap: break-word !important;"></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（6）污泥齡</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">由于生物脫磷系統主要是通過排除剩余污泥去除磷的，因此剩余污泥量的多少將決定系統的除磷效果。而污泥齡的長短對污泥的攝磷作用及剩余污泥的排放量有著直接的影響。一般來說，污泥齡越短，污泥含磷量越高，排放的剩余污泥量就越多，越可以取得較好的脫磷效果。短的污泥齡還有利于好氧段控制硝化作用的發生而利于厭氧段充分釋磷，因此，僅以除磷為目的的污水處理系統中，一般宜采用較短的污泥齡。但過短的污泥齡不僅會影響出水的BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">5</sub>和COD，甚至會使出水的BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">5</sub>和COD達不到要求。以除磷為目的的生物處理工藝，污泥齡一般控制在3.5～7d。一般來說，厭氧區的停留時間越長，除磷效果越好。但過長的停留時間并不會太多地提高除磷效果，而且會有利于絲狀菌的生長，使污泥的沉淀性能惡化，因此厭氧段的停留時間不宜過長。剩余污泥的處理方法也會對系統的除磷效果產生影響，因為污泥濃縮池中呈厭氧狀態會造成聚磷菌的釋磷，使濃縮池上清液和污泥脫水液中含有高濃度的磷，因此有必要采取合適的污泥處理方法，避免磷的重新釋放。</span></section><section><br/></section><section><section><section><section><p><span style="background-color: rgb(255, 255, 0);"><strong>七、生物除磷工藝</strong></span></p><p><span style="background-color: rgb(255, 255, 0);"><strong><br/></strong></span></p></section></section></section></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">廢水生物除磷工藝一般由兩個過程組成，即厭氧釋磷和好氧攝磷兩個過程。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">目前應用的生物除磷工藝主要有在生物除磷基本原理基礎上發展起來的弗斯特利普(Phostrip)除磷工藝和厭氧-好氧(An/O) 活性污泥法除磷工藝。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">1、弗斯特利普除磷工藝：</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">弗斯特利普(Phostrip) 除磷工藝是將生物除磷與化學除磷相結合的一種工藝，即在傳統活性污泥過程的污泥回流管線上增設厭氧釋磷池和混合反應池，采用生物和化學相結合的方法提高除磷效果。該工藝以生物除磷為主體，以化學除磷輔助去除厭氧釋磷后的上清液中的磷酸鹽，可以保證釋磷后的污泥主要用于對進水中的磷酸鹽進行吸收，因此可以達到更高的除磷效果。其工藝流程如圖所示。</span></section><section><p style="text-align:center"><img src="/admin888/ueditor/asp/upload/image/20210829/16302430502544507.png" title="image.png" alt="image.png" width="510" height="306" style="width: 510px; height: 306px;"/></p></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（1）該工藝各設備單元的功能：</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">①含磷廢水進入曝氣池，同步進入曝氣池的還有由除磷池回流的脫磷但含有聚磷菌的污泥。曝氣池的功能是:使聚磷菌過量地攝取磷，去除有機物(BOD 或COD)，還可能出現硝化作用。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">②從曝氣池流出的混合液(污泥含磷，廢水已經除磷)進人沉淀池I，在這里進行泥水分離，含磷污泥沉淀，已除磷的上清液作為處理水而排放。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">③含磷污泥進入除磷池，除磷池應保持厭氧狀態，即DO≈0，NOx≈0，含磷污泥在這里釋放磷，并投加沖洗水，使磷充分釋放，已釋放磷的污泥沉于池底，并回流至曝氣池，再次用于吸收廢水中的磷。含磷上清液從上部流出進入混合池。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">④含磷上清液進入混合池，同步向混合池投加石灰乳，經混合后進人攪拌反應池，使磷與石灰反應，形成磷酸鈣[Ca<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">3</sub>(PO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">4</sub>)<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">2</sub>]固體物質。此系用化學法除磷。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑤沉淀池Ⅱ為混凝沉淀池，經過混凝反應形成的磷酸鈣固體物質在這里與上清液分離。已除磷的上清液回流進人曝氣池，而含有大量Ca<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">3</sub>(PO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">4</sub>)<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">2</sub>的污泥排出，這種含有高濃度PO<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">3</sub><sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">-</sup>的污泥宜用作肥料。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（2）弗斯特利普除磷工藝已有很多應用實例。其主要特征有:</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">①生物除磷與化學除磷相結合，除磷效果良好，處理水中含磷量一般都低于1mg/L。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">②產生的剩余污泥中含磷量比較高，約為2.1%～7.1%，污泥回流應經過除磷池。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">③與完全的化學除磷法相比，所需的石灰用量比較低，一般介于21～31.8mg/[Ca(OH)<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">2</sub>·m<sup style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">3</sup>]。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">④活性污泥的SVI值<100mL/g，污泥易于沉淀、濃縮、脫水，污泥肥分高，絲狀菌難于增殖，污泥不膨脹，且易于濃縮脫水。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑤可以根據BOD/P的比值來靈活調節回流污泥與混凝污泥的比例。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑥流程復雜，運行管理比較復雜，由于投加石灰乳，致使運行費用也有所提高，基建費用高。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑦沉淀池I的底部可能形成缺氧狀態而產生釋放磷的現象，因此，應當及時排泥和回流。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; color: rgb(0, 0, 0); overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">2、厭氧-好氧活性污泥除磷工藝</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">厭氧-好氧活性污泥組合工藝( anaerobic/oxic,An/O)是直接在生物除磷基本原理的基礎上設計出來的，其工藝流程如圖所示。</span></section><section><p style="text-align:center"></p></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（1）工藝流程</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">An/O脫磷工藝主要由厭氧池、好氧池、二沉池構成，廢水和污泥順序經厭氧和好氧交替循環流動?；亓魑勰噙M人厭氧池可吸附一部分有機物并釋放出大量的磷，進人好氧池的廢水中的有機物得到好氧降解，同時污泥將大量攝取廢水中的磷，部分富磷污泥以剩余污泥排出，實現除磷的目的。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">①選擇An/O組合工藝的前提條件在An/O組合工藝中，一般進水要求有較高含量的易降解有機基質，這是采用An/O組合工藝的前提。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">②An/O組合工藝的特點：在厭氧好氧生物除磷(An/O) 組合工藝中，厭氧池應維持嚴格的厭氧狀態，要求池內基本沒有硝態氮(例如硝態氮濃度低于0.2mg/L)，溶解氧濃度低于0.4mg/L。厭氧池容積一般占總容積的20%，厭氧池一-般分格，每格都設有攪拌器，維持污泥懸浮狀態。厭氧池第一格的硝態氮濃度要求在0.3mg/L以下，最好為0.2mg/L以下，運行中要避免好氧池的硝化混合液進人厭氧池，并控制回流污泥的硝態氮含量。厭氧池分格有利于抑制絲狀菌的生長，產生沉降性能優越的污泥。</span><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.544px; overflow-wrap: break-word !important;"></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">好氧池可采用機械曝氣或擴散曝氣，實際應用中的溶解氧濃度控制在1.0mg/L以上，以保障有機底物的降解和磷的吸收。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">該工藝利用聚磷菌厭氧釋磷和好氧吸磷的特性，通過排放高含磷污泥達到除磷目的。若進水中的磷與有機底物濃度之比較高，由于有機底物負荷較低，剩余污泥量較少，因而較難達到穩定的處理效果，故該工藝尤其適于進水中磷與有機底物濃度之比很低的情況。由于An/O組合工藝的污泥齡短(2～6d)，系統往往達不到硝化，回流污泥也就不會攜帶硝酸鹽至厭氧區。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">厭氧-好氧活性污泥系統中強調了進水與回流污泥混合后維持厭氧狀態的必要性，這種厭氧狀態的維持不僅能促進聚磷菌的選擇性增強，而且所產生的污泥基本上無絲狀菌，活性高、密實、可快速沉淀。由于絲狀菌基本都是好氧菌，厭氧狀態對其不利，因此該工藝不僅可有效除磷，而且可改善污泥的性能。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">An/O組合工藝流程簡單，既無須投藥，也無須考慮內循環，因此，建設費用及運行費用都較低，而且由于無內循環的影響，厭氧反應器能夠保持良好的厭氧(或缺氧)狀態。</span></section><section><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; color: rgb(0, 0, 0); overflow-wrap: break-word !important;">（2）An/O 組合工藝具有如下優點：</span></strong></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">①污泥在反應器內的停留時間一般從2～6d，是比較短的。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">②反應器(曝氣池)內的污泥濃度一般在2700～3000mg/L之間。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">③BOD的去除率大致與一般的活性污泥系統相同。磷的去除率較好，處理水中的磷含量一般都低于1.0mg/L去除率在76%左右。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">④沉淀污泥(剩余污泥)中的含磷率約為4%，具有較高的肥效，可用作農肥。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑤由于整個系統中的活性污泥交替處在厭氧和好氧條件下，混合液的SVI值≤100mL/g，沉降性好，發生污泥膨脹的可能性較小。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">（3）本工藝具有如下問題：</strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">①除磷率難以進一步提高，因為微生物對磷的吸收即便是過量吸收，也是有一定限度的，特別是當進水BOD值不高或廢水中含磷量較高，即P/BOD值高時，由于污泥的產量低，將更是如此。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">②在沉淀池內容易產生磷的釋放，特別是當污泥在沉淀池內停留時間較長時更是如此，應注意及時排泥和回流。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（4）厭氧-好氧(An/O)生物除磷組合工藝的設計及其影響因素</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">厭氧-好氧(An/O)生物除磷組合工藝的設計計算中，反應池總有效容積的計算、需氧量及曝氣系統的計算等可參照傳統推流式活性污泥系統的設計;厭氧段的布置及反應池長、寬、深等具體尺寸計算等可參照缺氧-好氧(A/(0) 生物脫氮組合工藝的設計。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">①有機底物污泥負荷NTS 在An/O組合工藝中，由于聚磷菌厭氧釋磷時，需要攝取簡單有機物為自身碳源PHB，因此為了滿足聚磷菌對有機物的攝取，保證良好的除磷效果，有機底物污泥負荷NTS不應小于0.1kgBOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">5</sub>/(kgMLSS·d)。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">②污泥濃度XT和污泥回流比R在An/O組合工藝中，由于厭氧(An)段和好氧(O)段的活性污泥內微生物菌群都以異養菌為主，因此其濃度XT、污泥回流比R等參數與僅考慮異養除碳效能的傳統活性污泥過程相近，其中MLSS取2700～3000mg/L，R取50%～100 %。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">③污泥齡θc 在An/O組合工藝中，為了防止硝化過程的發生，其污泥齡僅以滿足聚磷菌和除碳異養菌為準，一般θc取2～6d。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">④水力停留時間(HRT)由于An/O組合工藝中的微生物菌群主要為異養菌，其對BOD5的去除率大致與傳統活性污泥過程相似，反應池內的水力停留時間較短，一般厭氧池An段的HRT為1～2h，好氧池O段的HRT為2～4h，總共3～6h，An段的HRT與O段的HRT的比值一-般為1 : (2～3)。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑤溶解性總磷與溶解性BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">5</sub>之比，為了滿足聚磷菌厭氧釋磷過程中對簡單有機底物的需求，要求廢水中溶解性總磷與溶解性BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">5</sub>的比值( 即S-TP/SBOD5)不大于0.06，磷的去除率達70%～80%，處理后出水的磷濃度一般小于1.0mg/L。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑥溶解氧DO在An/O組合工藝中，為了保持厭氧段的厭氧釋磷條件，要求其DO濃度約為0mg/L。為了滿足好氧段聚磷菌好氧吸磷對DO的需求，要求0段的DO濃度為2mg/L左右。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（5）厭氧-好氧(An/O)) 生物除磷組合工藝的發展</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">由于聚磷菌可直接利用的基質多為VFA類易降解有機基質，若原水中VFA類有機基質含量較低，則傳統An/O組合工藝除磷的效能將受到影響。針對這一問題，Barnard在傳統An/O組合工藝的基礎上進行改進，并提出了AP (activated primary)組合工藝，如圖所示。</span></section><section><p style="text-align:center"></p><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.544px; text-align: justify; overflow-wrap: break-word !important;"></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">AP組合工藝旨在通過對初沉污泥的發酵產生乙酸鹽等利于聚磷菌利用的低相對分子質量有機基質，從而利于后面的An/O系統的良好運行，使厭氧段的水力停留時間縮短至1h或更短。</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; color: rgb(0, 0, 0); overflow-wrap: break-word !important; background-color: rgb(255, 218, 81);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">3、常用的生物除磷工藝：</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（1）A/O工藝流程</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">厭氧/好氧活性污泥除磷系統(A/O)由前段厭氧池和后段好氧池串聯組成，A/O除磷工藝流程如圖所示。</span></section><section><p style="text-align:center"></p></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">前段為厭氧池，城市污水和回流污泥進入該池，并借助水下推進式攪拌器的作用使其混合?；亓魑勰嘀械木哿姿嵩趨捬醭乜晌杖コ徊糠钟袡C物，同時釋放出大量磷。然后混合液流人后段好氧池，污水中的有機物在其中得到氧化分解，同時聚磷菌將變本加厲，超量地攝取污水中的磷，然后通過排放高磷剩余污泥而使污水中的磷得到去除。好氧池在良好的運行狀況下，剩余污泥中磷的含量在2.5%以上。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">A/O生物除磷工藝的主要特點:</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">①工藝流程簡單。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">②厭氧池在前、好氧池在后，有利于抑制絲狀菌的生長?；旌弦旱腟VI小于100，污泥易沉淀，不易發生污泥膨脹，并能減輕好氧池的有機負荷。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">③在反應池內，水力停留時間較短，一般厭氧池的水力停留時間為1～2h，好氧池的水力停留時間為2～4h，總共為3～6h。厭氧池/好氧池的水力停留時間之比一般為1 : (2～3)。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">④剩余活性污泥含磷率高，一般為2.5%以上，故污泥肥效好。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑤除磷率難以進一步提高。當污水BOD濃度不高或含磷量高時，則P/BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;">5</sub>比值高，剩余污泥產量低，使除磷率難以提高。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">⑥當污泥在沉淀池內停留時間較長時，則聚磷菌會在厭氧狀態下產生磷的釋放，從而降低該工藝的除磷率，所以應注意及時排泥和使污泥回流。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; letter-spacing: 0.5px; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; overflow-wrap: break-word !important;">（2）Phostrip 工藝流程</span></strong></span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">Phostrip工藝是由Levin在1965年首先提出的，該工藝是在回流污泥的分流管線上增設一個脫磷池和化學沉淀池而構成的。</span></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">Phostrip工藝流程</span></section><section><p style="text-align:center"></p></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word !important;">該工藝將A2/O工藝的厭氧段改造成類似于普通重力濃縮池的磷解吸池，部分回流污泥在磷解吸池內厭氧放磷，污泥停留時間一般5～12h，水力表面負荷小于20m3/(m2·d)。經濃縮后污泥進入缺氧池，解磷池上層清液含有高濃度的磷，將此上層清液排人石灰混疑沉淀池進行化學處理生成磷酸鈣沉淀，該含磷污泥可作為農業肥料，而混凝沉淀池出水應流人初沉池再進行處理。Phostrip工藝不僅通過高磷剩余污泥除磷，而且還通過化學沉淀除磷。該工藝具有生物除磷和化學除磷雙重作用，所以Phostrip工藝具有高效除磷功能。</span></section><p><br/></p><p><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; letter-spacing: 0.5px; overflow-wrap: break-word 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