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{#vc_header_5e1f0a008ae83926 .header_subtitle{font-size:20px !important;}}</style> <div class="qfe_wrapper"> <h1 class="qfy_title left mobileleft"> <div class="qfy_title_inner" style="display:inline-block;position:relative;max-width:100%;"> <div class="header_title" style="font-family:微軟雅黑;font-size:26px;font-weight:normal;font-style:normal;color:#191919;"> 氯離子高于多少不能進生化？如何去除？ </div> </div> </h1> </div> </div> <div m-padding="0px 0px 0px 0px" p-padding="0 0 0 0" css_animation_delay="0" qfyuuid="qfy_column_text_mtoeb-c-9c" data-anitime="0.7" class="qfy-element qfy-text qfy-text-68107 qfe_text_column qfe_content_element newsdate " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:0;margin-bottom:20px;padding-top:0;padding-bottom:0;padding-right:0;padding-left:0;border-radius:0px;"> <div class="qfe_wrapper"> <div><span style="" class="qfy_no_editor pdate">2021/8/25</span></div> </div> </div> <div m-padding="0px 0px 70px 0px" p-padding="0 0 70px 0" css_animation_delay="0" qfyuuid="qfy_column_text_re2wu-c-9c" data-anitime="0.7" data-ani_iteration_count="1" class="qfy-element qfy-text qfy-text-85363 qfe_text_column qfe_content_element " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:10px;margin-bottom:0;padding-top:0;padding-bottom:70px;padding-right:0;padding-left:0;border-radius:0px;"> <div class="qfe_wrapper"> <section><section><section><section><section><section><article><section><section><span style="margin: 0px; padding: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; background-color: rgb(255, 255, 0); color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">氯離子是氯最為穩定的形態，一方面，由于微生物不能利用Cl-，所以不能通過生物法來去除Cl-，并且廢水中氯離子含量會抑制微生物的生長，阻礙生物法處理廢水效率！</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section></section><section><h2 style="margin: 0px 0px -1px; padding: 0px 5px 6px; font-weight: 400; font-size: 16px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; line-height: 20px; border-bottom-width: 2px; border-bottom-style: solid; border-bottom-color: rgb(204, 0, 0); display: inline-block;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0);"><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px;">1、影響機理</span></strong></span></h2></section></article></section></section></section></section></section></section><p></p><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">高濃度氯離子對廢水生物處理的毒害作用主要是通過升高的環境滲透壓而破壞微生物的細胞膜和菌體內的酶，從而破壞微生物的生理活動。舉例說明如下：</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">1、微生物在等滲透壓下生長良好．如微生物在質量為5～8.5g／L的NaCl溶液中；</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">2、在低滲透壓(p(NaCl)=0.1g／L)下，溶液水分子大量滲入微生物體內，使微生物細胞發生膨脹，嚴重者破裂，導致微生物死亡；</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">3、在高滲透壓(p(NaCl)=20g／L)下，微生物體內水分子大量滲到體外（即：脫水），使細胞發生質壁分離。</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">4、微生物的單位結構是細胞，細胞壁相當于半滲透膜，在氯離子濃度小于等于2000mg/L時，細胞壁可承受的滲透壓為0.5-1.0大氣壓，即使加上細胞壁和細胞質膜有一定的堅韌性和彈性，細胞壁可承受的滲透壓也不會大于5-6大氣壓。但當水溶液中的氯離子濃度在5000mg/L以上時，滲透壓大約將增大至10-30大氣壓，在這樣大的滲透壓下，微生物體內的水分子會大量滲透到體外溶液中，造成細胞失水而發生質壁分離，嚴重者微生物死亡。工程經驗數據表明：當廢水中的氯離子濃度大于2000mg/L時，微生物的活性將受到抑止，COD去除率會明顯下降；當廢水中的氯離子濃度大于8000mg/L時，會造成污泥體積膨脹，水面泛出大量泡沫，微生物會相繼死亡。</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">而室外給水排設計規范給的生化處理進水氯離子范圍是不大于4000mg/l，如圖所示：</span></section><section><br/></section><p></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(51, 51, 51); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; font-variant-numeric: normal; font-variant-east-asian: normal; letter-spacing: 0.544px; line-height: 27.2px; white-space: normal; widows: 1; text-align: center; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><img src="/admin888/ueditor/asp/upload/image/20210825/16298958441797574.png" title="image.png" alt="image.png" width="708" height="458" style="width: 708px; height: 458px;"/></p><p></p><section><br/></section><section><section><section><section><section><section><article><section><h2 style="margin: 0px 0px -1px; padding: 0px 5px 6px; font-weight: 400; font-size: 16px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; line-height: 20px; border-bottom-width: 2px; border-bottom-style: solid; border-bottom-color: rgb(204, 0, 0); display: inline-block;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0);"><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px;">2、抑制污泥活性的表現</span></strong></span></h2></section></article></section></section></section></section></section></section><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">1、當生化系統氯離子濃度大幅度突變時，污泥的碳化性能和硝化性能會很快減弱甚至消失，導致COD去除率明顯下降，硝化過程亞硝酸鹽累積，即使提高污水中的溶解氧，效果不明顯。也就是說，活性污泥對氯離子濃度具有一定的容忍性，當氯離子濃度超過一定值時，系統降解能力下降，直至系統失去處理能力。</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">2、氯離子突然變化比氯離子逐漸變化對系統的干擾更大。</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">3、隨著氯離子的升高，有機物降解速率下降，因此低F／M(養料與活性污泥在質量上的比值)更適合含氯離子廢水的處理。</span></section><section><br/></section><p></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(51, 51, 51); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; font-variant-numeric: normal; font-variant-east-asian: normal; letter-spacing: 0.544px; text-align: justify; white-space: normal; widows: 1; line-height: 1.75em; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">4、氯離子改變污泥中微生物的組成，改變了污泥的沉淀性和出水SS，導致污泥流失嚴重．活性污泥的濃度下降，污泥指數升高，30分鐘沉降率下降。</span></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(51, 51, 51); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; font-variant-numeric: normal; font-variant-east-asian: normal; letter-spacing: 0.544px; text-align: justify; white-space: normal; widows: 1; line-height: 1.75em; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></p><p></p><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">5、活性污泥鏡檢結果來看，低鹽度時顯示其中生物相比較豐富，絲狀細菌、菌膠團、原生動物種類繁多，活性污泥顆粒很大，菌膠團呈封閉狀，絮凝體具有一定的緊密度。隨著來水氯離子濃度的升高，當氯離子突變由原來的150mg／L增至1000mg／L時，絲狀菌及原生動物基本不存在，而菌膠團變得更為密實，此時絮體變得細小，異常緊密。污水中有機物的降解主要靠污水中大量微生物的共同作用完成，氯離子增加導致活性污泥中微生物中屬數量減少，從而使有機物降解速率下降。</span></section><p></p><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(51, 51, 51); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; font-size: 17px; font-variant-numeric: normal; font-variant-east-asian: normal; letter-spacing: 0.544px; line-height: 27.2px; text-align: justify; white-space: normal; widows: 1; background-color: rgb(255, 255, 255); box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></p><p></p><section><section><section><section><section><section><article><section><h2 style="margin: 0px 0px -1px; padding: 0px 5px 6px; font-weight: 400; font-size: 16px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; line-height: 20px; border-bottom-width: 2px; border-bottom-style: solid; border-bottom-color: rgb(204, 0, 0); display: inline-block;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(0, 0, 0);"><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px;">3、<span style="margin: 0px; padding: 0px; max-width: 100%; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">氯離子去除技術</span></span></strong></span></h2></section></article></section></section></section></section></section></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">目前專門為了去除氯離子使其達標排放而研發的技術是很少的，去除氯離子的目的大致有兩種：一是為了使廢水能滿足后續生物處理生物活性要求;二是為了達到廢水回用氯化物含量標準。氯離子去除原理主要有兩種：要么被其它陰離子替代;要么同其它陽離子一起去除。根據不同性質大體歸類為四種方式：沉淀鹽方式、分離攔截方式、離子交換方式、氧化還原方式。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(171, 25, 66);"><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">1、沉淀鹽方式</span></strong></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">采用Ag+或Hg+等與Cl-生成沉淀，再將沉降過濾，從而去除Cl-。沉淀鹽方式主要有化學沉淀法，關于該方法研究也很多。金艷等發明了處理一種氯堿行業高氯含汞廢水的系統，由于廢水中含氯離子濃度高達50000-60000mg/L，由于配合作用，汞主要以HgCl3+與Hg-Cl2-的非汞離子形態存在，經過一系列處理后，出水汞濃度可達1.5ppb，Cl-也得到了一定的去除。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">李文歆等利用化學沉淀法做了專業特征廢液中氯離子的處理的研究，氯離子去除率高達90%以上。該法具有操作簡單、污染小、去除率高等特點。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">化學沉淀法由于要加入沉淀試劑，如硝酸銀、硝酸汞等，這些沉淀劑的價格往往較高，導致其工業成本很高，應用不廣泛，基本僅限于實驗室使用。如果開發價格低廉的沉淀劑，由于化學沉淀法反應過程簡單、易操作，所以還是有很大的應用前景的。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(171, 25, 66);"><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">2、分離攔截方式</span></strong></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">主要采用蒸發濃縮、電吸附、膜過濾、溶劑萃取和復合絮凝劑絮凝等方法將Cl-分離去除。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">2.1 蒸發濃縮法</span></strong></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">對廢水升溫，由于無機鹽類氯化物沸點高于水，最后被濃縮結晶;氯化氫沸點相對較低，同水蒸氣等易揮發物質一同被去除。從而實現了氯離子與廢水的分離。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">江西理工大學材化學院科研人員發明了含銨含氯廢水處理并回收利用銨和氯的方法，利用該方法使得銨鹽和氯不僅得到有效分離，還能回收利用。該法有效去除了有色金屬冶煉過程中含銨含氯廢水中氯離子，并實現了經濟與環境的統一。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">泡菜生產過程主要產生的廢水類型有腌漬廢水、脫鹽廢水及脫鹽水、清洗水、沖洗水等，其中以腌漬廢水氯離子濃度可達153000mg/L，對部分量少的廢水可采用蒸發法。丁文軍等采用三效濃縮設備將鹽漬水濃縮至飽和狀態，再經結晶、離心分離等工序制得食鹽并回用于泡菜腌制。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">蒸發濃縮法適合于小水量高濃度的廢水，其操作簡單，效果明顯，在泡菜等行業應用較多;但對于水量較大廢水，其成本很高，相比其他處理方法不實用。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">2.2 電吸附法</span></strong></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">電吸附技術結合了電化學理論和吸附分離技術，通過對水溶液施加靜電場作用，在電極上加上直流電壓，在兩電級表面形成雙電層，由于雙電層具有電容的特性，因而能夠進行充電和放電過程，且溶液中離子不發生化學反應。在充電過程中吸附并保存溶液中離子，在放電過程中釋放能量和離子，使雙電層再生。其目前應用也比較多。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">魏鴻禮做了電吸附工藝去除再生水中氯離子的研究，結果表明，含氯離子平均為307mg/L的原水，產水平均為91mg/L，氯離子平均去除率為70.4%。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">電吸附法相比電解法，由于不發生化學反應，相對成本較低，且處理效果良好，而在回用水凈化中，其相對常規石灰軟化法工藝去除氯離子等鹽類效果更明顯，所以其回用水凈化中應用很廣。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">2.3 絮凝沉淀、溶劑萃取法</span></strong></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">絮凝沉淀主要利用絮凝劑作用氯離子，將其絮凝以至沉淀去除，如復合絮凝劑;溶劑萃取是利用萃取劑將含氯離子的化合物萃取去除。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">汪巍發明了一種用聚合硫酸亞鐵對含氯廢水進行絮凝沉淀的方法，該方法可把進水為500~1000mg/L含氯廢水，降低到0.4mg/L以下。雷春生等發明了一種由有機酸和無機鹽復配而成的復合除氯劑，實驗表明，該法可去除99.9%以上的氯離子。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">絮凝沉淀和溶劑萃取受試劑的影響，溶劑萃取僅適用于小水量情況，更多應用于實驗室;絮凝沉淀法在其成本較低的情況下，可能可應用于較大水量氯離子的去除，但目前應用并不廣泛。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; color: rgb(171, 25, 66);"><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; font-size: 15px; letter-spacing: 2px; box-sizing: border-box !important; overflow-wrap: break-word !important;">3、離子交換方式</span></strong></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">采用離子交換劑與氯離子進行交換替代氯離子，利用該方式的方法有離子交換樹脂法、水滑石法等。值得說明的是水滑石法，由于水滑石(LDHs)的結構特點使其層間陰離子可與各種陰離子，包括無機離子、有機離子、同種離子、雜多酸離子以及配位化合物的陰離子進行交換。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">胡靜等也研究了焙燒鎂鋁碳酸根水滑石(CLDH)對廢水中氯離子的去除效果。實驗表明，Cl-的去除率可達97%。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">水滑石法目前研究較多，其對氯離子的去除效果也較好，但多停留在實驗階段，工程應用很少。離子交換樹脂法用復床或混床，將氯離子去除，屬傳統工藝，設備投資較低，但陰離子交換樹脂容易飽和，需要再生。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">4、氧化還原方式</span></strong></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">采用電解或電滲析、還原方式將Cl-去除。應用方法有電解、電滲析、加氧化劑等。電解是當污水通電后，電解槽的陰陽級之間產生電位差，趨使污水中陰離子向陽極移動發生氧化反應，陽離子向陰極移動發生還原反應，從而使得廢水中的污染物在陽極被氧化，在陰極被還原，或者與電極反應產物作用，轉化為無害成分被分離除去。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">4.1 電滲析法</span></strong></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">電滲析以離子交換膜為滲析膜，以電能為動力。電滲析過程是電解和滲析擴散過程的組合。在外加直流電場作用下，陰、陽離子分別往陽極和陰極移動，由于陽離子膜理論上只允許陽離子通過，陰離子膜只允許陰離子通過，如果膜的固定電荷與離子電荷相反，則離子可以通過，反之則被排斥。由此來實現氯離子的去除。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">錢學玲等采用味精廢水-預處理-電滲析-厭氧-好氧工藝流程，整個工藝流程既保證了COD等的去除，又可使Cl-濃度從進水16.776g/L降至6g/L以下，從而達到了很好的綜合去除效果。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">電滲析法適合處理低濃度含氯廢水，水耗和電耗較大，成本較高，其對小水量的處理還是比較實用的。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><strong style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">4.2 電解、氧化劑法</span></strong></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">電解是當污水通電后，電解槽的陰陽級之間產生電位差，趨勢污水中陰離子向陽極移動發生氧化反應，陽離子向陰極移動發生還原反應，從而使得廢水中的污染物在陽極被氧化，在陰極被還原，或者與電極反應產物作用，轉化為無害成分被分離除去;氧化劑法是通過與氯離子發生氧化還原反應將氯離子去除的方法。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">李長俊等采用混凝絮凝-電解法聯用技術，實驗表明，Cl-濃度能從原水的136698.2mg/L降低到54205.5mg/L，能達到較好的去除效果。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;">電解法去除氯離子同樣存在成本高的問題，對小水量廢水應用有較好效果，相對于電滲析法其不存在膜堵塞問題，但運行費用相對較高，一般在廢水預處理后采用。氧化劑法目前應用也較少。</span></section><section><span style="margin: 0px; padding: 0px; max-width: 100%; box-sizing: border-box !important; word-wrap: break-word !important; font-size: 15px; color: rgb(0, 0, 0); letter-spacing: 2px;"><br/></span></section><section><strong><span 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