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{#vc_header_5e1f0a008ae83926 .header_subtitle{font-size:20px !important;}}</style> <div class="qfe_wrapper"> <h1 class="qfy_title left mobileleft"> <div class="qfy_title_inner" style="display:inline-block;position:relative;max-width:100%;"> <div class="header_title" style="font-family:微軟雅黑;font-size:26px;font-weight:normal;font-style:normal;color:#191919;"> 污水處理中COD和BOD之間的區別與聯系？ </div> </div> </h1> </div> </div> <div m-padding="0px 0px 0px 0px" p-padding="0 0 0 0" css_animation_delay="0" qfyuuid="qfy_column_text_mtoeb-c-9c" data-anitime="0.7" class="qfy-element qfy-text qfy-text-68107 qfe_text_column qfe_content_element newsdate " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:0;margin-bottom:20px;padding-top:0;padding-bottom:0;padding-right:0;padding-left:0;border-radius:0px;"> <div class="qfe_wrapper"> <div><span style="" class="qfy_no_editor pdate">2022/3/16</span></div> </div> </div> <div m-padding="0px 0px 70px 0px" p-padding="0 0 70px 0" css_animation_delay="0" qfyuuid="qfy_column_text_re2wu-c-9c" data-anitime="0.7" data-ani_iteration_count="1" class="qfy-element qfy-text qfy-text-85363 qfe_text_column qfe_content_element " style="position: relative;;;line-height:1.5em;;background-position:left top;background-repeat: no-repeat;;margin-top:10px;margin-bottom:0;padding-top:0;padding-bottom:70px;padding-right:0;padding-left:0;border-radius:0px;"> <div class="qfe_wrapper"> <p><span style="letter-spacing: 0.544px; text-align: justify; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0);">污水處理過程中，通常每個環節都會涉及水質檢測，在水質監測指標中，最常見也是最重要的兩個指標就是COD和BOD。那么這兩個指標的含義是什么，他們之間又有什么區別和聯系呢?</span></p><section><span style="font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box; overflow-wrap: break-word !important; text-align: left; background-color: rgba(42, 196, 119, 0.11);"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(42, 196, 119); letter-spacing: 1px; box-sizing: border-box !important; overflow-wrap: break-word !important;">什么是BOD？</span></strong></strong></span></section><p><section><br/></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">BOD即生化需氧量又稱生化耗氧量（Biochemical Oxygen Demand，簡寫為BOD）,是指在有氧的條件下，水中微生物分解有機物的生物化學過程中所需溶解氧的質量濃度。</span></section><section><br/></section><section><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">為了使BOD檢測數值有可比性，一般規定一個時間周期，并測定水中溶解氧消耗情況，一般采用五天時間，稱為五日生化需氧量，記作BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">5</sub>，相應地還有BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">10</sub>、BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">20</sub>。BOD以毫克/升或百分率、ppm表示。它是反映水中有機污染物含量的一個綜合指標。</span></section><section><span style="font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box; overflow-wrap: break-word !important; color: rgb(42, 196, 119); letter-spacing: 1px; text-align: left; background-color: rgba(42, 196, 119, 0.11);">什么是COD？</strong></span></section><section><br/></section></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(51, 51, 51); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">COD即化學需氧量（Chemical Oxygen Demand，簡寫為COD），是在一定的條件下，采用一定的強氧化劑處理水樣時，所消耗的氧化劑量。它反映了水中受物質污染的程度，化學需氧量越大，說明水中受有機物的污染越嚴重。</span></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(51, 51, 51); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><br/></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; clear: both; min-height: 1em; color: rgb(51, 51, 51); font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; text-align: justify; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em; box-sizing: border-box !important; overflow-wrap: break-word !important;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">COD以mg/L表示，據水質監測儀器檢測出的COD數值，可將水質可分為五大類：其中一類和二類COD≤15mg/L，基本上能達到飲用水標準；數值大于二類時為污染水質，其中三類COD≤20mg/L、四類COD≤30mg/L、五類COD≤40mg/L。COD數值越高，污染就越嚴重。</span></p><p><section><br/></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-size: 17px; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box; overflow-wrap: break-word !important; color: rgb(42, 196, 119); font-size: 15px; letter-spacing: 1px; text-align: left; background-color: rgba(42, 196, 119, 0.11);">BOD和COD的區別</strong></span></section><section><br/></section><section><span style="font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">1、從含義區分</strong></span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">在污水處理過程中，有機物質有上百種，對這些有機物質進行逐一分析，既耗時間，又耗藥品。經過研究發現，所有的有機物質都有二個共性，一是它們都由碳氫組成；二是絕大多數的有機物質能夠化學氧化或被微生物氧化，它們的碳和氫分別與氧形成無毒無害的二氧化碳和水。</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">污水中的有機物質不論是在化學氧化過程中還是在生物氧化過程中都要消耗氧，廢水中的有機物質愈多，則消耗的氧量也愈多，二者之間是呈正比例關系的。于是，將污水用化學藥劑氧化所消耗的氧量稱為COD（化學需氧量），將污水中微生物氧化所消耗的氧量稱為BOD（生化需氧量）。</span></section></p><section><span style="font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0);"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box; overflow-wrap: break-word !important; color: rgb(42, 196, 119); letter-spacing: 1px; background-color: rgba(42, 196, 119, 0.11);"><span style="font-family: 微軟雅黑, "Microsoft YaHei"; margin: 0px; padding: 0px; outline: 0px; max-width: 100%; color: rgb(112, 112, 112); letter-spacing: 0.5px; box-sizing: border-box !important; overflow-wrap: break-word !important;">2、從測定方法區分</span></strong><br/></span></section><p><section><br/></section></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important; clear: both; min-height: 1em; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">COD是化學需氧量，是用化學方法測定水中污染程度。BOD是生化需氧量，是用生物化學的方法測定水中污染物。</span></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important; clear: both; min-height: 1em; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em;"><br/></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important; clear: both; min-height: 1em; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">COD與BOD比較，COD的測定不受水質條件限制，測定的時間短。但是COD不能區分可被生物氧化的和難以被生物氧化的有機物，不能表示出微生物所能氧化的有機物量，而且化學氧化劑不僅不能氧化全部有機物，反而會把某些還原性的無機物也氧化了。所以采用BOD作為有機物污染程度的指標較為合適，在水質條件限制不能做BOD測定時，可用COD代替。水質相對穩定條件下，COD與BOD之間有一定關系：一般重鉻酸鉀法COD＞BOD5＞高錳酸鉀法COD。</span></p><p><section><br/></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">實際上，COD不只單單反應水中有機物，它還能表示水中具有還原性質的無機物質，如：硫化物、亞鐵離子、亞硫酸鈉等。比如污水中的亞鐵離子在中和池中沒有完全去除掉的話，在生化處理出水中，有亞鐵離子存在，出水COD可能會超標。</span></section><section><br/></section><section><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;"><strong style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box; font-size: 15px; color: rgb(42, 196, 119); letter-spacing: 1px; background-color: rgba(42, 196, 119, 0.11); overflow-wrap: break-word !important;">BOD和COD的關系</strong></span></section><section><br/></section></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important; clear: both; min-height: 1em; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">COD和BOD都是表征污水中有機污染物濃度的指標。污水中的有機物質，有的可以被生物氧化的(如葡萄糖和乙醇)，有的只能部分被生物氧化降解(如甲醇)，還有一部分有機物是不能被生物氧化降解的，并且還有一定的毒性(某些表面活性劑)。這樣，可以把污水中的有機物分成二個部分，可生化降解和不可生化降解的有機物。習慣上，COD基本上表示污水中所有的有機物，BOD是污水中可以生物降解的有機物，因此COD與BOD的差值，可表示污水中不能生物降解的有機物。</span></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important; clear: both; min-height: 1em; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em;"><br/></p><p style="margin: 0px 8px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important; clear: both; min-height: 1em; font-family: -apple-system, BlinkMacSystemFont, "Helvetica Neue", "PingFang SC", "Hiragino Sans GB", "Microsoft YaHei UI", "Microsoft YaHei", Arial, sans-serif; letter-spacing: 0.544px; white-space: normal; background-color: rgb(255, 255, 255); line-height: 1.75em;"><span style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; font-family: 微軟雅黑, "Microsoft YaHei"; color: rgb(0, 0, 0); box-sizing: border-box !important; overflow-wrap: break-word !important;">此外，5日生化需氧量與化學需氧量的比值(BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">5</sub>/COD)是污水可生化降解性的指標。公式表示為BOD<sub style="margin: 0px; padding: 0px; outline: 0px; max-width: 100%; box-sizing: border-box !important; overflow-wrap: break-word !important;">5</sub>/COD=(1-α)×(K/V)。式中：α為生化難以降解部分CODNB與COD之比；K為BOD5與最終生化需氧量BODU之比，為常數。從式中可以看出BOD5/COD值隨α增大而減小，故這一比值可反映污水可生化降解性的功能。通常以BOD5/COD=0.3為污水可生化降解的下限。</span></p><p><section><section><p style="margin-top: 0px; margin-bottom: 0px; padding: 0px 0.5em; outline: 0px; max-width: 100%; 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